Xanthate usually refers to a
salt with the formula ROCS
2−M
+ (R =
alkyl; M+ = Na
+, K
+). The name
xanthates is derived from
Greek ξανθός , meaning “yellowish, golden”, and indeed most xanthate salts are yellow. They were discovered and named in 1823 by the Danish chemist
William Christopher Zeise. These
organosulfur compounds are important in two areas, the production of
cellophane and related polymers from
cellulose and secondly in mining for the extraction of certain ores. They are also versatile intermediates in
organic synthesis. Xanthates also refer to
esters of xanthic acid. These esters have the structure ROC(=S)SR'.