In
chemistry, a
tetravalence is the state of an
atom with four
electrons available for
covalent chemical bonding in its
valence (outermost
electron shell). An example is
methane (CH
4): the tetravalent
carbon atom forms a covalent bond with four
hydrogen atoms. The carbon atom is called tetravalent because it forms 4 covalent bonds. A carbon atom has a total of six electrons occupying the first two shells, i.e., the K-shell has two electrons and the L-shell has four electrons. This distribution indicates that in the outermost shell there are one completely filled 's' orbital and two half-filled 'p' orbitals, showing carbon to be a
divalent atom. But in actuality, carbon displays tetravalency in the combined state. Therefore, a carbon atom has four valence electrons. It could gain four electrons to form the C
4- anion or lose four electrons to form the C
4+ cation. Both these conditions would take carbon far away from achieving stability by the
octet rule. To overcome this problem carbon undergoes bonding by sharing its valence electrons. This allows it to be covalently bonded to one, two, three or four carbon atoms or atoms of other elements or groups of atoms. Let us see how carbon forms the single, double and triple bonds in the following examples.