Illite is a non-expanding
clay crystalline mineral. Illite is a secondary mineral precipitate
phyllosilicate or layered alumino-silicate. Its structure is a 2:1 clay of silica tetrahedron –
alumina octahedron – silica tetrahedron layers. The space between individual clay crystals is occupied by poorly hydrated potassium cations which is responsible for the absence of swelling. Structurally, illite is quite similar to
muscovite with slightly more
silicon,
magnesium,
iron, and water and slightly less tetrahedral
aluminium and interlayer
potassium. The chemical formula is given as (K,H
3O)(Al,Mg,Fe)
2(Si,Al)
4O
10[(OH)
2,(H
2O)], but there is considerable ion (isomorphic) substitution. It occurs as aggregates of small
monoclinic grey to white crystals. Due to the small size, positive identification usually requires
x-ray diffraction or SEM-EDS (
automated mineralogy) analysis. Illite occurs as an alterated product of muscovite and
feldspar in
weathering and
hydrothermal environments; it may be a component of
sericite. It is common in sediments, soils, and argillaceous
sedimentary rocks as well as in some low grade
metamorphic rocks. The iron rich member of the illite group,
glauconite, in sediments can be differentiated by x-ray analysis.