A
counterion (pronounced as two words, i.e. "counter" "ion", and sometimes written as two words) is the
ion that accompanies an ionic species in order to maintain electric neutrality. In table salt (NaCl), the sodium
cation is the counterion for the chlorine
anion and vice versa. In a
charged transition
metal complex, a (i.e. non-coordinated) ion accompanying the complex is termed the
counterion. In the older literature, the term
gegenion (from
gegen which means counter in German) is sometimes used.