Alliin is a
sulfoxide that is a natural constituent of fresh
garlic. It is a derivative of the
amino acid cysteine. When fresh garlic is chopped or crushed, the enzyme
alliinase converts alliin into
allicin, which is responsible for the aroma of fresh garlic. Garlic has been used since antiquity as a therapeutic remedy for certain conditions now associated with
oxygen toxicity, and, when this was investigated, garlic did indeed show strong
antioxidant and
hydroxyl radical-scavenging properties, it is presumed owing to the alliin contained within.